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Student Number 90223009
Author Chih-Min Wang(王志銘)
Author's Email Address s0223009@cc.ncu.edu.tw
Statistics This thesis had been viewed 1675 times. Download 1008 times.
Department Chemistry
Year 2002
Semester 2
Degree Master
Type of Document Master's Thesis
Language zh-TW.Big5 Chinese
Title Synthesis, Crystal Structures and Properties of Organic-Inorganic Hybrid Compounds
Date of Defense 2003-06-23
Page Count 117
Keyword
  • coordination poolymor
  • metal phosphate
  • organic-inorganic hybrid
  • Abstract Abstract
    In the thesis, we report five novel metal phosphates have been syn- thesized under hydrothermal conditions and structurally characterized by single X-ray diffaction.
    Type Ⅰ:The first mixed-metal phosphate and metal phosphate incorporate isonicotinate ligand, CuVO2(HINT)(PO4), 1; Zn2(HINT)2(HPO4)2, 2.
    Type Ⅱ:Two mixed metal organic-inorganic hybrid compounds, CuVO2(4,4’-bipyridine)(PO4), 3; CuVO2(4,4’-bipyridine)(AsO4), 4, have a pillared layer structure.
    Type Ⅲ:The clustered vanadium phosphate, (4,4’H2bipyridine)[(VO2)4(PO4)2], 5, was a layer structure.
    The formulations were confirmed by single-crystal X-ray diffraction, Energy-dispersive X-ray fluorescence spectroscopy (EDS), powder X-ray diffraction, thermogravimetric analysis (TGA), elemental analysis (EA), magnetic susceptibility measurements, and solid state NMR spectroscopy.
    The compound 1 was the first mixed-metal phosphate. The structure consists of 2D neutral sheets of bimetallic oxide layers with the isonicotinate ligand being coordinated to copper in a bidentate fashion as a pendent group. The compound 2 was a noval zinc phosphate combined with isonicotinate ligand. Each Zn is tetrahedrally coordinated by three phosphate groups and one carboxylate group of the ligand in a mono- dentate fashion. So two compounds 1 and 2 being successfully synthesiz- ed would be the start for the study of the Metals/isonicotinate ligand/ phosphate system. The compounds 3 and 4 were isostructure linked through 4,4’-bipyridine pillars into a 3D framework. The compound 5 was a novel vanadium phosphate with V4O84+ clusters. The structure consists of phosphate-bridged vanadium (Ⅴ) clusters to form a layer structure in the presence of the protonated 4,4’-H2bipyridine as the structure-directing agent. 
    Table of Content 目錄
    摘要                                Ⅰ
    謝誌                                Ⅲ
    目錄                                Ⅳ
    圖目錄                               Ⅵ
    表目錄                               Ⅶ
    第一章 緒論
    1-1 前言                              1
    1-2 研究方式                            3
    1-3 使用的儀器及機型                        5
    1-4 單晶X-光繞射實驗與晶體結構解析                 6
    1-5 研究成果                            10
    第二章銅、釩混金屬與鋅磷酸鹽化合物的結構與性質探討
    2-1 前言                              16
    2-2 實驗部分                            17
    2-2-1 藥品                             17
    2-2-2 化合物的合成條件                       17
    2-2-3 粉末X-光繞射分析(PXRD)                   18
    2-2-4 化合物的元素分析                       18
    2-2-5 化合物的熱重分析 (TGA)                    20
    2-2-6 化合物的固態核磁共振測量 (NMR)                20
    2-2-7 化合物的晶體結構解析                     20
    2-3 結果與討論                           22
    2-3-1 晶體結構描述與討論                      22
    2-3-2 固態核磁共振分析                       25
    2-3-3 結論                             25
    第三章銅、釩混金屬磷酸鹽化合物的結構與性質探討
    3-1 前言                              40
    3-2 實驗部分                            40
    3-2-1 藥品                             40
    3-2-2 化合物的合成條件                       41
    3-2-3 粉末X-光繞射分析(PXRD)                    41
    3-2-4 化合物的磁性分析研究                     42
    2-2-5 化合物的熱重分析 (TGA)                    42
    3-2-6 化合物的元素分析                       42
    3-2-7 化合物的晶體結構解析                     43
    3-3 結果與討論                           45
    3-3-1 晶體結構描述與討論                      45
    3-3-2 結論                             46
    第四章釩磷酸鹽化合物的結構與性質探討
    4-1 前言                              56
    4-2 實驗部分                            56
    4-2-1 藥品                             56
    4-2-2 化合物的合成條件                       57
    4-2-3 粉末X-光繞射分析(PXRD)                    57
    4-2-4 化合物的元素分析                       58
    4-2-5 化合物的晶體結構解析                     58
    4-3 結果與討論                           59
    4-3-1 晶體結構描述與討論                      59
    4-3-2 結論                             60
    第五章結論                             69
    參考文獻                              70
    附錄(1)-CuVO2(HINT)(PO4)的晶體資料                73
    附錄(2)-Zn2(HINT)2(HPO4)2的晶體資料                79
    附錄(3)-CuVO2(4,4’-bpy)(PO4)的晶體資料              87
    附錄(4)-CuVO2(4,4’-bpy)(AsO4)的晶體資料             93
    附錄(5)-(H2C10H8N2)[(VO2)4(PO4)2]的晶體資料           100
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    Advisor
  • Kwang-Hwa Lii(李光華)
  • Files
  • 90223009.pdf
  • approve immediately
    Date of Submission 2003-07-09

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